Casting metals in limestone moulds
Abstract
Stone moulds were in common use around the world from the inception of metallurgy until the recent past, and most were certainly used to cast metal directly. Some ancient moulds from the eastern Mediterranean are of limestone and moreover, do seem to have been subjected to heat. However, there has been continuing scepticism amongst metallurgists and metalsmiths that moulds of thermally unstable stone such as these could have received molten copper. The discovery of a Bronze Age ingot mould from Ras Ibn
Hani, Syria, which clearly had been used to cast copper oxhide ingots inspired further experimentation into this subject. The mould was described as being of limestone, and casting replications were performed using a special limestone from Gozo, Malta which is used in the construction of ovens. A small oxhide ingot of copper was cast quite successfully, and both mould and operatives survived!
The limestone was shown to be highly fossiliferous and of fairly pure calcium carbonate, very similar to that used for some of the ancient moulds examined from the British Museum’s collection and for the Ras Ibn Hani ingot mould, suggesting a long continuity of deliberate choice of this type of limestone through the central and eastern Mediterranean for tasks where heat-resistance was important. Thus bronze can be cast in a limestone mould. However it is suggested that it was only really feasible to cast large simple shapes in single moulds, where loss of surface detail and limited gas generation would not be catastrophic.
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Beck M 1984, ‘Sardinian stone moulds’, in M S Balmuth and R J Rowlands (eds), Studies in Sardinian Archaeology (Ann Arbor), 163-208.
Blagg T and Read S 1977, ‘The Roman Pewter-Moulds from Silchester’, Antiquaries Journal 57, 270-6.
Branigan K 1974, Aegean metalwork of the Early and Middle Bronze Age (Oxford).
Catling H W 1964, Cypriot bronzework in the Mycenaean world (Oxford).
Craddock P T and Meeks N D 1987, ‘Iron in Ancient Copper’, Archaeometry 29(2), 187-204.
Dikaios P 1969, Excavations at Enkomi, 1948-1958 (Mainz).
Galon M and Duhamel du Monceau M 1764, The art of converting red, or rosette, copper into brass, from Descriptions des arts et métiers (Paris). Republished nd, ed and trans A P Woolrich and A den Ouden (Eindhoven).
Hemingway S 1996, ‘Minoan metalwork in post-palatial Palaikastro’, Annual of the British School at Athens 91, 213-52.
Largarce J 1986, ‘Herstellung von Kupferrohbarren in Ras Ibn Hani (Syrien)’, in A von Muller and W-D Dube (eds), Acta Praehistoria et Archaeologica 18 (Berlin), 85-90.
Lagarce J, Lagarce E, Bounni A and Saliby N 1983, ‘Les fouilles à Ras Ibn Hanie en Syrie (Campagnes de 1980, 1981 et 1982)’, Comptes Rendus, Academie des Inscriptions et Belles-Lettres 1983, 249-90.
Lo Schiavo F 1986, ‘Studies in Sardinian metallurgy’, in M S Balmuth (ed), Studies in Sardinian Archaeology II (Ann Arbor), 231-50.
Merkel R F 1986, ‘Ancient smelting and casting of “oxhide” ingots’, in M S Balmuth (ed), Studies in Sardinian Archaeology II (Ann Arbor), 251-71.
Muhly J D, Stech Wheeler T and Maddin R 1977, ‘The Cape Gelidonya shipwreck and the Bronze Age metals trade in the eastern Mediterranean’, Journal of Field Archaeology 4, 353-62.
Murray A S 1900, ‘Excavations at Enkomi’, in A S Murray, A H Smith and H B Walters, Excavations in Cyprus (London), 1-54.
Pernice E 1904, ‘Untersuchungen zur antiken Toreutik’, Jahreshefte des Österreichischen Archäologischen Institutes 7(2), 154-97.
Pernice E 1907, note in W Behnke (ed), Das Kunstgewerbe des Klassischen Altertums, Vol I, Chapter 3 (Berlin).
Schliemann H 1880, Ilios (London).
Shaw J W and Shaw M C (eds) 1995, Kommos I, (Princeton, NJ).
Thorpe J F and Whiteley M A 1938, Thorpe’s dictionary of applied chemistry (4th edn) 2 (London).
Tylecote R F 1976, A history of metallurgy (London).
Tylecote R F 1986, The prehistory of metallurgy in the British Isles (London).
Tylecote R F 1987, The early history of metallurgy in Europe (London).
Zwicker U, Virdis P and Ceruti M L 1980, ‘Investigations on copper ore, prehistoric copper slag and copper ingots from Sardinia’, in P T Craddock (ed), Scientific studies in early mining and extractive metallurgy (London: British Museum Occasional Paper 20), 135-63.